In order to improve the effectiveness of mobile cloud computing in Device-to-Device (D2D) communication network, a computation offloading scheme based on the time switch policy for energy harvesting was proposed. Firstly, the computational tasks needed to be migrated of a traffic-limited smart mobile terminal were sent to an energy-limited smart mobile terminal in the form of Radio-Frequency (RF) signals through D2D communication, and the time switch policy was used by the energy-limited smart mobile terminal for the energy harvesting of received signals. Then, the extra traffic consumption was paid by the energy-limited terminal for the relay tasks of traffic-limited terminal to the cloud server. Finally, the proposed scheme was modeled as a non-convex optimization problem for minimizing terminal energy and traffic consumption, and the optimal scheme was obtained by optimizing the time switch factor and the harvest energy allocation factor of the energy-limited terminal, and the transmission power of the traffic-limited terminal. The simulation results show that, compared with non-cooperative scheme, the proposed scheme can effectively reduce the terminal's limited resource overhead by the computation offloading through reciprocal cooperation.