Node representation learning has been widely applied in machine learning tasks, such as node classification, clustering and link prediction, since it can encode graph structure data information into low-dimensional potential space. In complex networks, nodes are interacted through not only low-order interactions, but also higher-order interactions formed by special connection modes. The higher-order interactions of a complex network are also called motifs. A node classification algorithm Fusing 2-connected Motif-structure Information (FMI) was proposed to use motif information among nodes to obtain node representation for node classification tasks. Firstly, the 2-connected motifs in the network were counted. A measure index of node importance, named motif-ratio, was proposed by using the motif information in the node; and a sampling probability was calculated according to the motif-ratio to carry out neighborhood sampling. A weighted auxiliary graph was constructed to fuse the low-order relations and the high-order relations of network nodes to aggregate neighborhoods weightedly. The node classification was performed on 5 datasets, Cora, Citeseer, Pubmed, Wiki and DBLP. By comparing with 5 classical baseline algorithms, the proposed algorithm FMI shows better performance on Accuracy, F1-score and other indicators.